Oligomerization oscillations of L-lactic acid in solution.
نویسندگان
چکیده
We employ high-performance liquid chromatography with diode array, evaporative light scattering, and mass spectrometric detection to monitor the oligomerization of L-lactic acid in pure acetonitrile and in 70% aqueous ethanol. The production of higher oligomers appears to proceed in an oscillatory fashion. A model is presented that involves the formation of aggregates (micelles), which catalyze the oligomerization.
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عنوان ژورنال:
- The journal of physical chemistry. A
دوره 115 50 شماره
صفحات -
تاریخ انتشار 2011